Sunday, 15 December 2013

Molecular Spectroscopy (Organic Chemistry) Syllabus M.Sc.(APPLIED CHEMISTRY) 3rd-III Sem Syllabus for DAVV Indore


DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus
M.Sc. (APPLIED CHEMISTRY) Fourth-3th-III Semester Curriculum/ Syllabus
MAP-301: Molecular Spectroscopy (Organic Chemistry) Syllabus

Unit -I ltraviolet and Visible spectroscopy: 

Fundamentals, effect of solvent and extending conjugation on electronic transitions, ultraviolet bands for carbonyl compounds, unsaturated carbonyl compounds, dienes, conjugated polyenes, Fieser Woodward rules for conjugated dienes and carbonyl compounds,ultraviolet spectra of aromatic compounds. Steric effect in biphenyls

Unit -II Infrared Spectroscopy:

  Characteristic vibrational frequencies of alkanes, alkenes, alkynes, aromatic compounds, alcohols, ethers, phenols and amines. Detailed study of vibrational frequencies of carbonyl compounds (ketones, aldehydes, esters, amides, acids, anhydrides,lactones, lactams and conjugated carbonyl compounds). Effect of hydrogen bonding and solvent effect on vibrational frequencies, overtones, combination bands and Fermi resonance

Unit –III Nuclear Magnetic Resonance Spectroscopy: 

General introduction and definition, chemical shift, spin-spin interaction, shielding mechanism, mechanism of measurement, chemical shift values and correlation for protons bonded to carbon (aliphatic, olefinic, aldehydic and aromatic) and other nuclei (alcohols, phenols, enols, carboxylic acids, amines, amides & mercapto), chemical exchange, effect of deuteration, Stereochemistry, hindered rotation, Karplus curvevariation of coupling constant with dihedral angle,NMR shift reagents,Solvent effects, Nuclear overhauser effect (NOE).
Carbon-13 NMR Spectroscopy: General considerations, chemical shift (aliphatic olefinic , alkyne, aromatic, heteroaromatic and carboynl carbon), coupling constants. Two dimensional NMR spectroscopy:COSY, HETCOR, NOESY, DEPT, HMBC and HMQC techniques

Unit- IV Mass Spectrometry :

 Introduction, ion production EI, CI, FD, ESI and FAB, ion analysis, ion abundance, Mass spectral fragmentation of organic compounds, common functional groups, molecular ion peak, metastable ion peak, Mc Lafferty rearrangement , Nitrogen rule, High resolution mass spectrometry. Combined problems based on UV, IR, NMR and Mass spectral techniques

Books Suggested

1. R.M. Silverstein, G.C. Bassler and T.C. Morrill, Spectrometric Identification of Organic Compounds, John Wiley
2. R.J. Abraham, J. Fisher and P. Loftus, Introduction to NMR spectroscopy, Wiley
3. J.R. Dyer, Application of Spectroscopy of Organic Compounds, Prentice Hall
4. D.H. Williams, I. Fleming, Spectroscopic Methods in Organic Chemistry, Tata McGraw-Hill
5. Banwell, Fundamentals of Molecular Spectroscopy, Tata McGraw Hill
6. G. Aruldhas, Molecular Structure and Spectroscopy, Prentice Hall

Photochemistry Syllabus M.Sc.(APPLIED CHEMISTRY) 3rd-III Sem Syllabus for DAVV Indore

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus
M.Sc. (APPLIED CHEMISTRY) Fourth-3th-III Semester Curriculum/ Syllabus
MAP-302: Photochemistry Syllabus


UNIT-I Photochemical Reactions

Interaction of electromagnetic radiation with matter, types of excitations, fate of excited molecule, quantum yield, transfer of excitation energy, actinometry.

UNIT-II Determination of Reaction Mechanism

Classification, rate constants and life times of reactive energy state determination of rate constants of reactions. Effect of light intensity on the rate of photochemical reactions, Types of photochemical reactions-photo dissociation, gas-phase photolysis.

UNIT-III Photochemistry of Alkene

Intramolecular reactions of the olefinic bond-geometrical isomerism, cyclisation reactions, rearrangement of 1,4- and 1,5-dienes. Photochemistry of Aromatic Compounds Isomerisations, Additions and Substitutions.

UNIT-IV Photochemistry of Carbonyl Compounds

Intramolecular reactions of carbonyl compounds-saturated, cyclic and acyclic,,γ- unsaturated and α,- unsaturated compounds, cyclohexadienones. Intermolecular cycloaddition reactions dimerisations and oxetane formation.
Miscellaneous Photochemical Reactions
Photo-Fries reactions of anilides, Photo-Fries rearrangement. Barton reaction. Singlet molecular oxygen reaction. Photochemical formation of smog. Photodegration of polymers. Photochemistry of vision

Books Suggested

1. K.K. Rothagi-Mukheriji, Fundamentals of photochemistry, Wiley-Eastern.
2. A Gilbert and J. Baggott, Essentials of Molecular Photochemistry, Blackwell Scientific Publication.
3. N.J. Turro, Molecular Photochemistry, Benjamin.
4. A. Cox and T. Camp, Introductory Photochemistry, McGraw Hill.
5. R.P. Kundall and A. Gilbert, Photochemistry, Thomson Nelson.
6. J. Coxon and B.Holtom, Organic Photochemistry, Cambridge University Press.
7. C H Dupuoy and O L Chapman Molecular Reactions and Photochemistry, Prentice Hall
8. J Kagan, Organic Photochemistry, Academic Press.

Diffraction Techniques and ESCA Syllabus M.Sc.(APPLIED CHEMISTRY) 3rd-III Sem Syllabus for DAVV Indore

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus
M.Sc. (APPLIED CHEMISTRY) Fourth-3th-III Semester Curriculum/ Syllabus
MAP-303: Diffraction Techniques and ESCA Syllabus


Unit-I X-ray Diffraction

Bragg condition, Miller indices, Laue Method, Bragg method, Debye Scherrer method of X-ray structural analysis of crystals, index reflections, identification of unit cells from systematic absences in diffraction pattern, Structure of simple lattices and X-ray intensities, structure factor and its relation to intensity and electron density, phase problem. Description of the procedure for an X-ray structure analysis, absolute configuration of molecules.

Unit-II Electron Diffraction

Scattering intensity vs. scattering angle, Wierl equation, measurement technique, elucidation of structure of simple gas phase molecules. Low energy electron diffraction and structure of surfaces.

Unit-III Neutron Diffraction

 Scattering of neutrons by solids measurement techniques, Elucidation of structure of magnetically ordered unit cells.

Unit IV Photoelectron Spectroscopy

Basic principles; photo-electric effect, ionization process, Koopman's theorem. Photoelectron spectra of simple molecules, ESCA, chemical information from ESCA. Auger electron spectroscopy-basic idea.

Saturday, 14 December 2013

Bioinorganic Chemistry Syllabus M.Sc.(APPLIED CHEMISTRY) 3rd-III Sem Syllabus for DAVV Indore


DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus
M.Sc. (APPLIED CHEMISTRY) Fourth-3th-III Semester Curriculum/ Syllabus
MAP-304: Bioinorganic Chemistry Syllabus


Unit I Electron Transfer in Biology

Structure and function of metal of proteins in electron transport processes cytochrome's and ionsulphure proteins, synthetic models. Biological nitrogen fixation, and its mechanism, nitrogenase, Chemical nitrogen fixation.

Unit II Metalloporphyrins

 Structure and optical spectra; heme proteins: magnetic susceptibility, epr and electronic spectra; hemoglobin and myoglobin: molecular structures, thermodynamics and kinetics of oxygenation, electronic and spatial structures, synthetic oxygen carriers, model systems; iron enzymes, peroxidase, catalase and cytochrome P-450

Unit III Metalloenzymes

Copper enzymes, superoxide dismutase, cytochrome oxidase and ceruloplasmin; Coenzymes; Molybdenum enzyme: xanthine oxidase; Zinc enzymes: carbonic anhydrase, carboxy peptidase and interchangeability of zinc and cobalt in enzymes; Vitamin B12 and B12 coenzymes; Iron storage, transport, biomineralization and siderophores, ferritin and transferrins..

Unit IV Metal Ions in  Biological Systems

Bulk and trace metals with special reference to Na, K, Mg, Ca, Fe, Cu, Zn, Co, and K+/Na+ pump.

Text Books

1. S. J. Lippard & J. M. Berg. Principles of Bioorganic Chemistry, Panima Publ. Corpn. (2005).
2. E.-I. Ochiai. Bioinorganic Chemistry – An Introduction, Allyn and Bacon Inc. (1977).
3. M. N. Hughes. The Inorganic Chemistry of Biological Processes, Wiley (1981).
4. R.P. Hanzlik. Inorganic Aspects of Biological and Organic Chemistry, Academic Press (1976)

MAP-305 Polymers Syllabus M.Sc.(APPLIED CHEMISTRY) 3rd-III Sem Syllabus for DAVV Indore

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus
M.Sc. (APPLIED CHEMISTRY) Fourth-3th-III Semester Curriculum/ Syllabus
MAP-305: Polymers Syllabus


Unit-I

[A] Basic concepts: 

Monomers, repeat units, degree of polymerization, Linear, branched and network polymers, Classification of polymers. Inorganic Polymers special characteristics, classification, homo and hetero atomic polymers.

[B] Polymerization:

condensation, addition, radical chain-ionic and co-ordination and copolymerization. Polymerization conditions and polymer reactions. Polymerization in homogeneous and heterogeneous systems.

 Unit-II

[A] Polydispersion-average molecular weight concept:

average molecular weights. Number, weight and viscosity Polydispersity and molecular weight  distribution. The practical significance of molecular weight. Measurement of molecular-weights. End-group, viscosity, light scattering, osmotic and ultracentrifugation methods.

 [B] Analysis and testing of polymers:

Chemical analysis of polymers, spectroscopic methods, Xray diffraction study, Microscopy. Thermal analysis and physical testing-tensile strength. Fatigue, impact, Tear esistance, Hardness and abrasion  resistance.

Unit-III : Polymer Processing

Plastics, elastomers, fibers. Compounding. Processing techniques. Clendering, die casting, rotational casting, film casting, injection moulding, blow moulding, extrusion moulding, thermoforming, foaming, reinforcing and fire spining

Unit-IV  Structure, Properties and Application of Polymers

Structure, Properties and Applications of:
[A] Functional polymers: Fire retarding polymers and Electrically conducting polymers.
[B] Biomedical polymers: Contact lens, dental polymers, artificial heart and kidney,
[C] Polymers based on boron-borazines, boranes , carboranes,
[D] Polymers based on Silicon, silicone's polymetalloxanes and polymetallosiloxanes,
[E] Polymers based on Phosphorous-Phosphazenes, Polyphosphates

Suggested Books:

1. Polymer Science, V. R. Gowariker, N. V. Viswanathan and J. Sreedhar, Wiley-Eastern.
2. Textbook of Polymers Science, F.W. Billmeyer Jr., Wiley.
3. Contemporary Polymer Chemistry, H.R. Al cock and F.W. Lambe, Prentice Hall.
4. Developments in Inorganic polymer Chemistry, M.F. Lappert and G.J. Leigh.
5. Inorganic polymers- N.H. Ray.
6. Inorganic polymers, Graham and Stone.
7. Inorganic polymers, J. E. Mark, H. R. Allcok and R. West

MAP-306 Unit Operations and Unit Processes Syllabus M.Sc.(APPLIED CHEMISTRY) 3rd-III Sem Syllabus for DAVV Indore

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus
M.Sc. (APPLIED CHEMISTRY) Fourth-3th-III Semester Curriculum/ Syllabus
MAP-306: Unit Operations and Unit Processes Syllabus

Unit I : Fluid Mechanics:

Fluid Statics and Its Applications, Fluids-Flow Phenomena, Basic Equations of Fluid Flow, Flow of Incompressible Fluid in Conduits and Thin Layers, Flow of Compressible Fluids, Flows Past Immersed Bodies, Transportation and Metering of Fluids, Agitation and Mixing of Liquids 

Unit II : Heat Transfer and Its Applications

 Heat Transfer by Conduction, Principle of Heat Flow in Fluids, Heat Transfer to Fluids without Phase Change, Heat Transfer to Fluids with Phase Change, Radiation Heat Transfer, Heat- Exchange equipment, Evaporation

Unit III Mass Transfer and Its Applications I

Equilibrium-Stage Operations, Physical distillation equipment, sieve plates, typical leaching equipment, terminology for stage-contact plants, Material balances , enthalpy balances, operating- line diagrams. Determination of number of ideal stages ( Mccabe-Thiel method and Absorption factor method), Numericals.

Unit IV Maas Transfer and its applications II

Distillation, flash distillation continuous distillation with reflux ( rectification ) material balances in plate columns, Gas absorption, Adsorption, membrane separation processes.

Book:

Warren L. McCabe, Julian C. Smith, Peter Harriott, Unit Operations of Chemical Engineering, Fifth Edition.

MAP-307 PRACTICAL Syllabus M.Sc.(APPLIED CHEMISTRY) 3rd-III Sem Syllabus for DAVV Indore

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus
M.Sc. (APPLIED CHEMISTRY) Fourth-3th-III Semester Curriculum/ Syllabus
MAP-307: PRACTICAL Syllabus

(A) Interpretations of Electronic, Infra-red, NMR, ESR, Mössbauer, Mass and XPS spectra

(B) Electronic Spectroscopy

  • i. Determination of kPa of an indicator (e.g. methyl red) in (a) aqueous and (b) micellar media.
  • ii. Determination of stoichiometry and stability constant of Ferricisothicoyanation complex ion in solution.
  • iii. Electronis spectral studies for transition metal complexes.