MCH-403 Analytical Chemistry Syllabus M.Sc.(CHEMISTRY) 4th-IV Sem Syllabus for DAVV Indore Affiliated Institutions

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (CHEMISTRY) Fourth-4th-IV Semester Curriculum/ Syllabus

MCH-403: Analytical Chemistry Syllabus

Unit -I Statistical tests and Error Analysis:

Accuracy, precision, classification of errors, significant figures and computation, mean deviation and standard deviation, Least square methods, regression coefficient , F-test, t-test and Chi-test. 

 Sampling and Sample Treatment: Factors involved in effective sampling, good samples; Representative and homogeneous,

samples of mixtures.

Unit –II Spectrochemical and Thermal Methods :

Spectrophotometry: Quantities principles of absorption, instrumentation, single beam, double

beam, determination of pKa value of an indicator, detectors, applications.

Atomic spectroscopy: Principles of emissions, atomic emission spectroscopy and flame emission

spectroscopy, monochromator, detector, types of interferences,

Thermal methods of analysis: Principles and instrumentation of TG and DTA. Complementary

nature of TG and DTA. Differential scanning calorimeter (DSC). Applications of thermal

methods in analytical chemistry .

Unit –III Electroanalytical Methods:

Theory of electrogravimetric analysis, electrode reactions, over potential, Cyclic voltammetry,

Linear-scan voltammetry, Pulse voltammetric methods, stripping methods.

Coulometry : Coulometrc titrations and controlled- potential electrolysis.

Unit - IV Separation Techniques :

Classification of chromatographic separations. Theory of chromatography. Applications of

chromatographic methods: Adsorption and partition chromatography. Ion exchange

chromatography , LC, HPLC and GC, Column matrices, Detectors. Affinity and chiral

columns.

Principles of analytical separations, liquid –liqid extraction : Distribution coefficient,

distribution ratio, solvent extraction of metals, analytical separations, multiple batch extractions,

countercurrent distribution., multiple extractions.

Books Suggested

1. Gary D.Christian, Analytical Chemistry, John-Wiley

2. H.A.Willard, L.L.Merrit, and J.A.Dean, Instrumental Methods of Analysis, Van

Nostrand, New York, 1986.

3. D.A.Skoog & D.M.West Principles of Instrumental Analysis. Holt Rinahart Winston,

New York, 1988.

4. K A Robinsons Chemical Analysis, Harper Collins Publishers, NewYork.

5. A.J. Bard and L. R. Faulkner, Electrochemical Methods: Fundamentals and Applications,

John Wiley & Sons: New York.