Bioinorganic Chemistry Syllabus M.Sc.(APPLIED CHEMISTRY) 3rd-III Sem Syllabus for DAVV Indore

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (APPLIED CHEMISTRY) Fourth-3th-III Semester Curriculum/ Syllabus

MAP-304: Bioinorganic Chemistry Syllabus

Unit I Electron Transfer in Biology

Structure and function of metal of proteins in electron transport processes cytochrome's and ionsulphure proteins, synthetic models. Biological nitrogen fixation, and its mechanism, nitrogenase, Chemical nitrogen fixation.

Unit II Metalloporphyrins

 Structure and optical spectra; heme proteins: magnetic susceptibility, epr and electronic spectra; hemoglobin and myoglobin: molecular structures, thermodynamics and kinetics of oxygenation, electronic and spatial structures, synthetic oxygen carriers, model systems; iron enzymes, peroxidase, catalase and cytochrome P-450

Unit III Metalloenzymes

Copper enzymes, superoxide dismutase, cytochrome oxidase and ceruloplasmin; Coenzymes; Molybdenum enzyme: xanthine oxidase; Zinc enzymes: carbonic anhydrase, carboxy peptidase and interchangeability of zinc and cobalt in enzymes; Vitamin B12 and B12 coenzymes; Iron storage, transport, biomineralization and siderophores, ferritin and transferrins..

Unit IV Metal Ions in  Biological Systems

Bulk and trace metals with special reference to Na, K, Mg, Ca, Fe, Cu, Zn, Co, and K+/Na+ pump.

Text Books

1. S. J. Lippard & J. M. Berg. Principles of Bioorganic Chemistry, Panima Publ. Corpn. (2005).
2. E.-I. Ochiai. Bioinorganic Chemistry – An Introduction, Allyn and Bacon Inc. (1977).
3. M. N. Hughes. The Inorganic Chemistry of Biological Processes, Wiley (1981).
4. R.P. Hanzlik. Inorganic Aspects of Biological and Organic Chemistry, Academic Press (1976)

MAP-305 Polymers Syllabus M.Sc.(APPLIED CHEMISTRY) 3rd-III Sem Syllabus for DAVV Indore

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (APPLIED CHEMISTRY) Fourth-3th-III Semester Curriculum/ Syllabus

MAP-305: Polymers Syllabus

Unit-I

[A] Basic concepts: 

Monomers, repeat units, degree of polymerization, Linear, branched and network polymers, Classification of polymers. Inorganic Polymers special characteristics, classification, homo and hetero atomic polymers.

[B] Polymerization:

condensation, addition, radical chain-ionic and co-ordination and copolymerization. Polymerization conditions and polymer reactions. Polymerization in homogeneous and heterogeneous systems.

 Unit-II

[A] Polydispersion-average molecular weight concept:

average molecular weights. Number, weight and viscosity Polydispersity and molecular weight  distribution. The practical significance of molecular weight. Measurement of molecular-weights. End-group, viscosity, light scattering, osmotic and ultracentrifugation methods.

 [B] Analysis and testing of polymers:

Chemical analysis of polymers, spectroscopic methods, Xray diffraction study, Microscopy. Thermal analysis and physical testing-tensile strength. Fatigue, impact, Tear esistance, Hardness and abrasion  resistance.

Unit-III : Polymer Processing

Plastics, elastomers, fibers. Compounding. Processing techniques. Clendering, die casting, rotational casting, film casting, injection moulding, blow moulding, extrusion moulding, thermoforming, foaming, reinforcing and fire spining

Unit-IV  Structure, Properties and Application of Polymers

Structure, Properties and Applications of:
[A] Functional polymers: Fire retarding polymers and Electrically conducting polymers.
[B] Biomedical polymers: Contact lens, dental polymers, artificial heart and kidney,
[C] Polymers based on boron-borazines, boranes , carboranes,
[D] Polymers based on Silicon, silicone's polymetalloxanes and polymetallosiloxanes,
[E] Polymers based on Phosphorous-Phosphazenes, Polyphosphates

Suggested Books:

1. Polymer Science, V. R. Gowariker, N. V. Viswanathan and J. Sreedhar, Wiley-Eastern.
2. Textbook of Polymers Science, F.W. Billmeyer Jr., Wiley.
3. Contemporary Polymer Chemistry, H.R. Al cock and F.W. Lambe, Prentice Hall.
4. Developments in Inorganic polymer Chemistry, M.F. Lappert and G.J. Leigh.
5. Inorganic polymers- N.H. Ray.
6. Inorganic polymers, Graham and Stone.
7. Inorganic polymers, J. E. Mark, H. R. Allcok and R. West

MAP-306 Unit Operations and Unit Processes Syllabus M.Sc.(APPLIED CHEMISTRY) 3rd-III Sem Syllabus for DAVV Indore

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (APPLIED CHEMISTRY) Fourth-3th-III Semester Curriculum/ Syllabus

MAP-306: Unit Operations and Unit Processes Syllabus

Unit I : Fluid Mechanics:

Fluid Statics and Its Applications, Fluids-Flow Phenomena, Basic Equations of Fluid Flow, Flow of Incompressible Fluid in Conduits and Thin Layers, Flow of Compressible Fluids, Flows Past Immersed Bodies, Transportation and Metering of Fluids, Agitation and Mixing of Liquids 

Unit II : Heat Transfer and Its Applications

 Heat Transfer by Conduction, Principle of Heat Flow in Fluids, Heat Transfer to Fluids without Phase Change, Heat Transfer to Fluids with Phase Change, Radiation Heat Transfer, Heat- Exchange equipment, Evaporation

Unit III Mass Transfer and Its Applications I

Equilibrium-Stage Operations, Physical distillation equipment, sieve plates, typical leaching equipment, terminology for stage-contact plants, Material balances , enthalpy balances, operating- line diagrams. Determination of number of ideal stages ( Mccabe-Thiel method and Absorption factor method), Numericals.

Unit IV Maas Transfer and its applications II

Distillation, flash distillation continuous distillation with reflux ( rectification ) material balances in plate columns, Gas absorption, Adsorption, membrane separation processes.

Book:

Warren L. McCabe, Julian C. Smith, Peter Harriott, Unit Operations of Chemical Engineering, Fifth Edition.

MAP-307 PRACTICAL Syllabus M.Sc.(APPLIED CHEMISTRY) 3rd-III Sem Syllabus for DAVV Indore

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (APPLIED CHEMISTRY) Fourth-3th-III Semester Curriculum/ Syllabus

MAP-307: PRACTICAL Syllabus

(A) Interpretations of Electronic, Infra-red, NMR, ESR, Mössbauer, Mass and XPS spectra

(B) Electronic Spectroscopy

• i. Determination of kPa of an indicator (e.g. methyl red) in (a) aqueous and (b) micellar media.
• ii. Determination of stoichiometry and stability constant of Ferricisothicoyanation complex ion in solution.
• iii. Electronis spectral studies for transition metal complexes.