MCH-203: PHYSICAL CHEMISTRY Syllabus MSc CHEMISTRY 2nd- II SemesterSyllabus for DAVV Indore Affiliated Institutions

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (CHEMISTRY) Second-2nd- II Semester Curriculum/ Syllabus

MCH-203: PHYSICAL CHEMISTRY-II Syllabus

Unit-I : Chemical Dynamics

Chemical kinetics: Empirical rate laws, Arrhenius equation, theories of reaction rates, determination of reaction mechanisms.

Kinetics of inorganic mechanisms : Hydrogen- Bromine reaction, Hydrogen- Chlorine Reaction. Decomposition of nitrogen pentaoxide, Decomposition of Ozone.

Kinetics of organic Decompositions : Pyrolysis of acetaldehyde, decomposition of ethane.

Unit-II : Surface Chemistry and Catalysis

Adsorption :Gibbs adsorption isotherm, BET equation and estimation of surface area .

Micelles:Surface active agents, classification of surface active agents, micellization, critical micellar concentration (CMC), factors affecting the CMC of surfactants, thermodynamics of micellization

Concepts of catalysis: Homogenous catalysis, kinetics of enzyme reactions,

Unit –III : Complex and Fast Reaction

Complex Reactions: Opposing reactions, Complex reactions, Parallel reactions , kinetics of free radical polymerization

Fast reactions: Experimental techniques for fast reactions viz., flow method, relaxation method, flash photolysis

Unit-IV: Applied Electrochemistry

Electrochemistry: Nernst equation, electrode kinetics, electrical double layer, Debye-Hückel theory. Voltammetry, Current voltage relationship, characteristics of DME, half-wave potential. Amperometric titrations.

Corrosion: Introduction to corrosion, forms of corrosion, Corrosion monitoring and prevention methods

Books Suggested

1. P.W. Atkins , Physical Chemistry, ELBS.

2. A.K. Chandra, Introduction to Quantum Chemistyry, Tata Mc Graw Hill.

3. Ira N. Levine, Quantum Chemistry, Prentice Hall.

4. K.J. Laidler, Chemical Kinetics. McGraw-Hill.

5. V. Moraoi, Micelles, Theoretical and Applied Aspects, Plenum.

6. A. J. Bard and L. R. Faulkner, Electrochemical Methods: Fundamentals and Applications, John Wiley & Sons: New York.

MCH-202: ORGANIC CHEMISTRY-II Syllabus M.Sc.(CHEMISTRY) 2nd-II Sem Syllabus for DAVV Indore Affiliated Institutions

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (CHEMISTRY) Second-2nd- II Semester Curriculum/ Syllabus

MCH-202: ORGANIC CHEMISTRY-II Syllabus

Unit-I

Common organic reactions and their mechanisms, base catalysed reactions, Stork Enamine  reaction, acid catalysed reactions, reactions of carboxylic acids and their derivatives Reagents in organic synthesis and relevant name reactions, organotransition metal reagents, some transition metal organometallic reactions, phosphorus containing reagents, organosulphur compounds, silicon reagents, boron containing reagents

Unit-II

Eletrophilic aromatic substitution- the arenium ion mechanism, orientation and reactivity, Ipso substitution, aromatic rearrangements Aromatic nucleophilic substitution-SNAr mechanism, SN1 mechanism, benzyne mechanism

Unit-III

Stereochemistry and mechanism of addition to carbon-carbon multiple bonds, addition reactions of alkenes and alkynes involving electrophiles, Birch reduction, epoxidation of alkenes Addition to carbon-hetero multiple bonds, addition to carbonyl compounds, metal hydride reduction, Meerwein-Ponndorf-Verley reduction, Wittig reaction

Unit-IV

Pericyclic reactions, conservation of molecular orbital symmetry, electrocyclic reactions, cycloaddition, sigmatropic rearrangements, the ene reaction, Mobius – Huckel analysis (PMO approach), correlation diagram method

Books Suggested

1. J. March., Advanced Organic Chemistry: Reactions, Mechanisms and Structure, John Wiley

2. P. S. Kalsi. Stereochemistry, Conformation and Mechanism, New Age International

3. Peter Sykes, A guide book to mechanism in Organic chemistry, Orient-Longmans

4. S. M. Mukherji and S. P. Singh, Reaction Mechanism in Organic Chemistry, Macmillan

5. F. A. Carey and R. J Sundberg, Advanced Organic Chemistry, Part A and B, Plenum

6. P. S. Kalsi., Organic Reactions and their Mechanisms, New Age International

MCH-201: INORGANIC CHEMISTRY- II Syllabus M.Sc.(CHEMISTRY) 2nd-II Sem Syllabus for DAVV Indore Affiliated Institutions

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (CHEMISTRY) Second-2nd- II Semester Curriculum/ Syllabus

MCH-201: INORGANIC CHEMISTRY- II Syllabus

Unit-I :Electronic Spectra and Magnetic Properties of Transition Metal Complexes :

Spectroscopic ground states, correlation. Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1-d9 states), calculations of 10Dq, B and β parameters, charge transfer spectra, anomalous magnetic moments, Orbital contribution to magnetic moment, magnetic exchange coupling and spin crossover.

Unit-II : Metal π-Complexes

Metal carbonyl, structure and bonding, vibrational spectra of metal carbonyls for bonding and structural elucidation, important reactions of metal carbonyls; preparation, bonding structure and important reaction of transition metal nitrosyl, dinitrogen and dioxgen complexes; tertiary phosphine as ligand.

Unit-III : Boranes

Classification, preparation, reactivity, bonding and topology of Boranes, carboranes metalloboranes and metallocarbonaes.

Unit-IV : 

Metal Clusters, Chains and Fullerenes Compounds with metal-metal multiple bonds. Isopoly and heteropoly acids and their salts. Fullerenes

Books Suggested :

1. Advanced Inorganic Chemistry, F.A. Cotton and Wilkinson, John Wiley.

2. Inorganic Chemistry, J.E. Huhey, Harpes & Row.

3. Chemistry of the Elements. N.N. Greenwood and A. Earnshow, Pergamon.

4. Inorganic Electronic Spectroscopy, A.B.P. Lever, Elsevier.

5. Magnetiochemistry, R.1. Carlin, Springer Verlag.

6. Comprehensive Coordiantion Chemistry eds., G. Wilkinson, R.D. Gillars and J.A. Mc Cleverty,Pergamon.