MAP-406 Chemical Reaction Engineering Syllabus M.Sc.(APPLIED CHEMISTRY) 4th-IV Sem Syllabus for DAVV Indore

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (APPLIED CHEMISTRY) Fourth-4th-IV Semester Curriculum/ Syllabus

MAP-406: Chemical Reaction Engineering Syllabus

Unit I : Introduction and material balances for chemical reactors.

Scope, kinetics of complex reactions, concept of stationary state , The rate expression, Material balance in chemical reactors, Batch reactors, Plug flow reactors (PFRs), Continuous stirred tank reactors (CSTRs), numerical problems.

Unit II : Calculation of reactor volume and residence time

Residence time of batch reactors, constant volume batch reactor, constant pressure batch reactor, plug flow reactors (PFRs) , continuous stirred tank reactors (CSTRs) , Comparison of PFRs and CSTRs, Reactors in series, The recycle reactor, numerical problems

Unit III :Multiple reactions

Parallel reactions, Batch reactors and PFRs, Parallel reactions of different order, Series reactions, CSTRs, Comperision of PERS and CSTRs, Problems

Unit IV: The energy balance and temperature effects

Temperature dependence of reaction rate, Reversible endothermic reactions, reversible exothermic reactions, energy balance ( CSTR, PFR and batch reactors ), Steady-state multiplicity in CSTRs, Multistage adiabatic PFR, Problems

Books:

1. Ian S Metcalfe, Chemical reaction engineering 1997
2. J M Smith, Chemical Engineering Kinetics, Third edition .

MAP-405 Industrial Catalysis Syllabus M.Sc.(APPLIED CHEMISTRY) 4th-IV Sem Syllabus for DAVV Indore

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (APPLIED CHEMISTRY) Fourth-4th-IV Semester Curriculum/ Syllabus

MAP-405: Industrial Catalysis Syllabus

Unit I : Catalysis in solutions

Introduction, Acid-base catalysis, catalysis by electron transfer, Organometallic catalysis, Catalysis by macromolecules, Phase transfer catalysis, Catalysis by micelles

Unit II : Catalysis by enzymes

Composition and structure of enzymes, Reactions catalyzed by enzymes, Nature of catalytic sites: the Uniqueness of enzymes as catalysts, Examples of enzyme structure and catalysis, Supported Enzymes,

Unit III : Catalysis by polymers:

Nature of Polymers, Attachment of Catalytic Groups to Polymer Supports, Catalysis in Polymer Gels, Adsorption and Kinetics of Polymer-Catalyzed Reactions, Interactions of Catalytic Groups: the Role of the Support, Bifunctional and Multifunctional Catalysis, Porous Polymers and Surface Catalysis, Intraparticle Transport Influence, Applications of Polymer Catalysts.

Unit IV : Catalysis by Nanomaterials 

Structures of Crystalline Solids, important preparative techniques for Nanomaterials, Catalysis by nanometerials and nano metal oxides, Structures of Zeolites (Crystalline Alluminosilicates), Families of Zeolites, Adsorption and Diffusion in Zeolites, The Solvent like Nature of Zeolite Pores, Catalysis by Zeolites, Nonzeolite Molecular Sieves, Clays and Other Layered Materials

Unit V : Catalysis on Surfaces

Nature of surfaces, Charcaterization of surfaces, important surface characterization techniques such as LEED, XPS, BET surface area measurements, XRD Kinetics of few important surface reactions like epoxidation , ammoximation and alkylation.

Book:

Catalytic Chemistry, Bruce-gates, John Wiley & Sons

MAP-404 Bioorganic Chemistry Syllabus M.Sc.(APPLIED CHEMISTRY) 4th-IV Sem Syllabus for DAVV Indore

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (APPLIED CHEMISTRY) Fourth-4th-IV Semester Curriculum/ Syllabus

MAP-404: Bioorganic Chemistry Syllabus

Unit-I: Introduction 

Basic Consideration, Proximity effects and molecular adoption.
Enzymes: Introduction, Chemical and Biological catalysis, remarkable properties of enzymes, Nomenclature and classification, concept and identification of active site by use of inhibitors, reversible & irreversible inhibition.

Unit-II : Kinds of Reactions Catalyzed by Enzymes

B-cleavage and consideration, some isomerization and rearrangement reactions. Enzyme catalyzed carboxylation and decarboxylation.
Mechanism of Enzyme action: Transition state theory, Orientation and steric effect, acid-base catalysis, covalent catalysis.
Co-Enzyme Chemistry: Cofactors as derived from vitamins, coenzymes, prosthetic groups, apoenzymes, Structure and biological functions of coenzyme A.

Unit-III : Enzyme Models :

Host guest chemistry, Chiral recognition and catalysis, molecular recognition, molecular asymmetry and prochirality, Biomimetic chemistry, crown ethers, cryptates, cyclodextrins, cyclodextrin based enzyme models, Calixarenes, ionophores, micelles synthetic enzyme or synzymes.

Unit-IV : Biotechnological Application of enzymes:

 Large scale production and purification of enzymes, techniques and methods of immobilization of enzyme activity, application of immobilized enzymes, effect of immobilization on Enzyme activity, application of immobilized enzymes. Clinical uses of enzymes, enzyme therapy, enzymes and recombinant DNA technology.

Books Suggested

1. Bioorganic chemistry:A Chemical Approch to Enzyme action,Hermann Dugas and
C.Penny, Springer-Verag.
2. Understanding Enzymes, Trevor Palmer, Prentice Hall
3. Enzyme Chemistry: Impact and applications, Ed Collin J Suckling, Chapman and Hall
4. Enzyme mechanism a Ed. M.I.Page and A. Williams, Royal society of chemistry
5. Fundamentals of Enzymology, N.C. Price and L. Stevens, Oxford University Press.
6. Enzymattic Reaction Mechanism C. Walsh,W.H. Freeman.
7. Enzyme Structure and Mechanism A Fersht, W.H.Freeman.
8. Biochemistry : The Chemical reaction of leaving cells, D.E.Metzler, Academic Press.
9. Biochemistry(4th edn.) Stryer, L.W.; H.Freeman & Co.(1995)
10. Understanding Enzymes Palmer, T.; Prantice Hall (1995).

MAP-402 Environmental Chemistry Syllabus M.Sc.(APPLIED CHEMISTRY) 4th-IV Sem Syllabus for DAVV Indore

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (APPLIED CHEMISTRY) Fourth-4th-IV Semester Curriculum/ Syllabus

MAP-402: Environmental Chemistry Syllabus

Unit I : Environment

Introduction. Composition of atmosphere, vertical temperature, temperature inversion, heat budget of the earth, atmospheric system, vertical stability atmosphere, Biochemical cycles of C, N, P, S and O. Biodistribution of elements.
Hydrosphere
Chemical composition of water bodies-lakes, streams, rivers and wet lands etc.

Hydrological cycle
Aquatic pollution – Inorganic,organic, pesticide, agriculture, industrial and sewage, detergents, oil spills and oil pollutants. Water quality parameters – dissolved oxygen, biochemical oxygen demand, solids, metals, content of chloride, sulphate, phosphate, nitrate and microorganisms. Water quality standards. Analytical methods of measuring BOD, DO, COD, F, Oils, metals (As, Cd, Cr, Hg, Pb, Se etc.),residual chloride and chlorine demand. Purification and treatment of water.

Unit II : Soils

Composition, micro and macro nutrients, pollution – fertilizers, pesticides, plastics and metals. Waste treatment.
Atmosphere : Chemical composition of atmosphere – particles, ions and radicals and their formation. Chemical and photochemical reactions in atmosphere, smog formation, oxides of N, C, S, O and their effect, pollution by chemicals, petroleum, minerals, chlorofluorohydrocarbons. Green house effect, acid rain, air pollution controls and their chemistry. Analytical methods for measuring air pollutants. Continuous monitoring instruments.

Unit III : Industrial Pollution

Cement, sugar, distillery, drug, paper and pulp, thermal power plants, nuclear power plants, metallurgy. Polymers, drugs etc.
Environmental disasters – Cherbonyl, Three mile island, Seveso and minamata disasters,Japan tsunami

Unit IV : Environmental Toxicology

Toxic heavy metals : Mercury, lead, arsenic and cadmium. Causes of toxicity. Bioaccumulation, sources of heavy metals. Chemical speciation of Hg, Pb, As, and Cd. Biochemical and damaging effects.
Toxic Organic Compound : Pesticides, classification, properties and uses of organochlorine and ionospheres pesticides detection and damaging effects.

Books Suggested

1. Environmental Chemistry, S.E. Mahan, Lewis Publishers.
2. Environmental Chemistry, Sharma & Kaur, Krishna Publishers.
3. Environmental Chemistry, A.K. De, Wiley Eastern
4. Environmental Pollution Analysis, S.M. Khopkar, Wiley Eastern
5. Standard Method of Chemical Analysis, F.J. Welcher Vol. III, Van Nostrand Reinhold Co.
6. Environmental Toxicology, Ed. S. Landsberger and M. Creatchman, Gordon and Breach Science Publication.
7. Enviromental Chemistry, C. Baird, W.H. Freeman.

MAP-401 Solid State Chemistry Syllabus M.Sc.(APPLIED CHEMISTRY) 4th-IV Sem Syllabus for DAVV Indore

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (APPLIED CHEMISTRY) Fourth-4th-IV Semester Curriculum/ Syllabus

MAP-401: Solid State Chemistry Syllabus

Unit I : Solid State Reactions

General principles, experimental procedure, co-precipitation as a precursory to solid state reactions, kinetics of solid state reactions.

Unit II : Crystal Defects and Non-Stoichiometry

Perfect and imperfect crystals, intrinsic and extrinsic defects-point defects, line and plane defects, vacancies-Schottky detects and Frenkel defects. Thermodynamics of Schottky and Frenkel defect formation, colour centres, non-stoichiometry and defects.

Unit III : Electronic Properties and Band Theory

Metal,s insulators and semiconductors, electronic structure of solidsband theory band structure of metals, insulators and semiconductors, Intrinsic and extrinsic semiconductors, doping semiconductors, p-n junctions, super conductors. Optical properties-Application of optical and electron microscopy. Magnetic Properties-Classification of materials : Effect of temperature calculation of magnetic moment, mechanism of ferro and anti ferromagnetic ordering super exchange.

Unit IV : Organic Solids

Electrically conducting solids. organic charge transfer complex, organic metals, new superconductors. 

Books Suggested

1. Solid state chemistry and its applications, A.R. West. Peenum.
2. Principles of the Solid State, H.V. Keer, Wiley Eastern.
3. Solid State Chemistry, N.B. Hannay.
4. Solid State Chemistry, D.K. Chakrabarty, New Wiley Eastern.