MCH-205: Organometallic Chemistry Syllabus M.Sc.(CHEMISTRY) 2nd-II Sem Syllabus for DAVV Indore Affiliated Institutions

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (CHEMISTRY) Second-2nd- II Semester Curriculum/ Syllabus

MCH-205: Organometallic Chemistry Syllabus

Unit I : Main Group Organometallics

Synthesis and reactions of organolithium compounds; Synthesis and reactions of organomagnesium compounds; Organometallics of zinc and mercury: preparation, structure, bonding and reactions of aluminum organyls; Thallium(I) organyls (synthesis of TlCp); Organyls of sodium, synthesis of NaCp; Silicon and tin organyls of coordination number 4. 

 Unit II : Transition Metal–Carbon Bond

Transition Metal–Carbon σ-Bond: Brief review of metal alkyl compounds; transition metalcarbene and transition metal-carbyne compounds; transition metal vinylidene and transition metal allenylidene compounds. Cyclopropenyl cation (C3R3 +) as a ligand; C4R4 as a ligand (R = H, Me, Ph)

Unit III : Syntheses of Cyclopentadienyl and Arene Metal Analogues

Synthesis and reactions of cyclopentadienyl metal carbonyls, cyclopentadienyl metal hydrides, cyclopentadienyl metal halides, arene metal carbonyls, η6-arene-chromium tricarbonyl in organic synthesis.

Unit IV : Applications to Organic Synthesis and Homogeneous Catalysis

(a) In Organic Synthesis: Hydrozirconation of alkenes and alkynes; Carbonylation of Colman’s  reagent; η4-diene iron-tricarbonyls in organic synthesis

(b) In Catalysis: Asymmetric hydrogenation; synthesis of acetic acid and glycol (Monsanto acetic acid process); Arylation/vinylation of olefins (Heck reaction); Wacker process (olefin oxidation); Asymmetric epoxidation.

Text Books

1. C. Elschenbroich. Organometallics (3rd edn.), Wiley-VCH Publication (2006).

2. C. Elschenbroich & A. Salzer. Organometallics – A Concise Introduction (2nd edn.),VCH Publication (1992).

3. F. Mathey & A. Sevin. Molecular Chemistry of the Transition Elements, John Wiley (1996).

4. F. A. Cotton & G. Wilkinson. Advanced Inorganic Chemistry (5th edn.), John Wiley (1988).

5. R. C. Mehrotra & A. Singh. Organometallic Chemistry: A Unified Approach (2nd edn.), New

Age International (2000).

MCH-205-Organometallic-Chemistry-Syllabus-Msc-CHEMISTRY-2nd-II-Sem-Syllabus-for-DAVV-Indore-Affiliated-Institutions 

MCH-206: Computational Methods in Chemistry Syllabus M.Sc.(CHEMISTRY) 2nd-II Sem Syllabus for DAVV Indore Affiliated Institutions

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (CHEMISTRY) Second-2nd- II Semester Curriculum/ Syllabus

MCH-206: Computational Methods in Chemistry Syllabus

(This is a theory cum-laboratory course with more emphasis on laboratory work). 

Unit-I : Introduction to computers and Computing

Basic structure and functioning of computer with a PC as illustrative example. Operating systems with DOS as an example Introduction to UNIX and WINDOWS.

Unit-II : Computer Programming in FORTRAN/C/BASIC

(the language features are listed here with reference to FORTRAN. The instructor may choose another language such as BASIC or C the features may be replaced appropriately). Constants and variables. Operations and symbols Expressions. Arithmetic assignment statement. Input and output Format statement. Termination statements. Branching statements as IF or GO TO statement. LOGICAL variables. Double precession variables. Subscripted variables and DIMENSION. DO statement FUNCTION AND SUBROUTINE. COMMON and DATA statement

Unit-III : Programming in Chemistry

Developing of small computer codes (FORTRAN/C/BASIC) involving simple formulae in Chemistry, such as Van der Waals equation. Chemical kinetics (determination of Rate constant) Radioactive decay (Half Life and Average Life). Determination Normality, Molarity nd Molality of solutions. Evaluation Electronegativity of atom and Lattice Energy from experimental

determination of molecular weight and percentage of element organic compounds using data from experimental metal representation of molecules in terms of elementary structural features such as bond lengths, bodn angles, dihedral angles, etc.

Unit-IV : Use of Computer programmes

Operation of PC. Data Processing. Running of standard Programs and Packages such as MS WORD, MS EXCEL special emphasis on calculations and chart formations. X-Y plot. Use of Programs Chemcraft, Molden and PovRey.

Book Suggested :

• Fundamentals of Computer : V. Rajaraman (Prentice Hall)
• Computers in Chemistry : K.V. Raman (Tata Mc Graw Hill)
• Computer Programming in FORTRAN IV-V Rajaraman (Prentice Hall)

MCH-207: PRACTICAL Syllabus M.Sc.(CHEMISTRY) 2nd-II Sem Syllabus for DAVV Indore Affiliated Institutions

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (CHEMISTRY) Second-2nd- II Semester Curriculum/ Syllabus

MCH-207: PRACTICAL Syllabus

Chromatography Separation of cations and anions by

Column Chromatography : Ion exchange.

Preparations

Preparation of selected inorganic compounds and their studies by I.R. electronic spectra, Mossbauer, E.S.R. and magnetic susceptibility measurements. Handling of air and moisture sensitive compounds.

Organic Synthesis

Aldol condensation Dibenzal acetone from benzaldehyde. Sandmeyer reactuion : p- Chlorotoluene from p-toluidine. Acetoacetic ester Condensation : Synthesis of ethyl-nbutylacetoacetate by A.E.E. condensation. Connizzaro reaction : 4-Chlorobenzaldehyde as substrate. Friedel Crafts reaction : b-Benzoyl propionic acid from succinic anhydride and benzene. Aromatic electrophilic sustitutions : Synthesis of p-nitroaniline and p-bromoaniline. The Products may be Characterized by Spectral Techniques.

Quantitative Analysis

Determination of the percentage or number of hydroxyl groups in an organic compound by acetylation method. Estimation of amines/phenols using bromate bromide solution/or acetylation method. Determination of lodine and Saponification values of an oil sample. Determination of DO, COD and BOD of water sample.

Conductometry

i. Determination of the velocity constant, order of the reaction and energy of activation for saponification of ethyl acetate by sodium hydroxide conductometrically.

ii. Determination of solubility and solubility product of sparingly soluble salts 9e.g. PbSO4, BaSO4) conductometrically.

iii. Determination of the strength of strong and weak acid in a given mixture conductometrically.

iv. to study of the effect of solvent on the conductance of AgNO3/acetic acid and to determine the degree of dissociation and equilibirum constant in different solvents and in their mixtures (DMSO, DMF, dioxane, acetone, water) and to test the validity of Debye- Huckel-Onsager theory.

v. Determination of the activity coefficient of zinc ions in the solution of 0.002 M zinc sulphate using Debye Huckel's limiting law.

Potentiometry/pH metry

1. Determination of strengths of halides in a mixture potentiometrically.

2. Determination of the valency of mercurous ions potentiometrically.

3. Determination of the strength of strong and weak acids in a given mixture using a

potentiometer/pH meter.

4. Determination of temperature dependence of EMF of a cell.

5. Determination of the formation constant of silver-ammonia complex and stoichiometry of

the complex potentiometrically.

6. Acid-base titration in a non-aqueous media using a pH meter.

7. Determination of activity and activity coefficient of electrolytes.

8. Determination of the dissociation constant of acetic acid in DMSO. DMF, acetone adn

dioxane by titrating it with KOH.

9. Determination of the dissociation constnat of monobasic/dibasic acid by albert-Sderjeant

method.

10. Determination of thermodynamic constants, DG, DS, and DH for the reaction by e.m.f.

method. Zn + H2SO4 -> ZnSO4 + 2 H

Polarimetry

1. Determination of rate constant for hydrolysis/inversion of sugar using a polarimeter.

2. Enzyme kinetics-inversion of sucrose.

Books Suggested

1. Vogel's Textbook of Quantitative Analysis, revised, J. Bassett, R.C. Denney, G.H. Jeffery and J. Mendham, ELBS.

2. Synthesis and Characterization of Inorganic Compounds, W.L. Jolly. Prentice Hall.

3. Experiments and Techniques in Organic Chemistry, D.P. Pasto, C. Johnson and M. Miller, Prentice Hall.

4. Macroscale and Microscale Organic Experiments, K.L. Williamson, D.C. Health.

5. Systematic Qualitative Organic Analysis, H. Middleton, Adward Arnold.

6. Handbook of Organic Analysis-qualitative and Quantitative. H. Clark, Adward Arnold.

7. Vogel's Textbook of Practical Organic Chemistry, A.R. Tatchell, John Wiley.

8. Practical Physical Chemistry, A.M. James and F.E. Prichard, Longman.

9. Findley's Practical Physical chemistry, B.P. Levitt, Longman.

10. Experimental Physical Chemistry, R.C. Das and B. Behera, Tata McGraw Hill. 

MCH-204: Magnetic Resonance and Mössbauer Spectroscopy Syllabus M.Sc.(CHEMISTRY) 2nd-II Sem Syllabus for DAVV Indore Affiliated Institutions

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (CHEMISTRY) Second-2nd- II Semester Curriculum/ Syllabus

MCH-204: Magnetic Resonance and Mössbauer Spectroscopy Syllabus

Unit-I: Nuclear Magnetic Resonance Spectroscopy

Nuclear spin, nuclear resonance, saturation, shielding of magnetic nuclei, chemical shift and its measurements, factors, influencing chemical shift, deshielding, spin-spin interactions, factors influencing coupling constant "j" Classification (AXB, AMX, ABC, A2B2 etc.). spin decoupling; basic ideas about instrument, NMR studies of nuclei other than protin-13C, 19F and 31P. FT  MR.

Unit-II : Nuclear Quadrupole Resonance Spectroscopy

Quadrupole nuclei, quadrupole moments, electric field gradient, coupling constant, splitting. Applications.

Unit-III : Electron Spin Resonance Spectroscopy

Basic principles, Hyperfine coupling, Isotropic and anisotropic hyperfine coupling contstnats, spin polarization for atoms and transition metal ions, spin-orbit coupling and significance of gtensors, factors affecting the 'g' value. Zero field splitting and Kramer's degeneracy.. spin Hamiltonian, spin densities and Mc Connell relationship. Applications.

Unit IV : Mössbauer Spectroscopy

Basic principles, spectral parameters and spectrum display. Application of the techniqueto the studies of (1) bonding and structures of Fe+2 and Fe+3 compounds including those of intermediate spin, (2) Sn+2 and Sn+4 compounds nature of M-L bond, coordination number, structure and (3) detection of oxidation state and inequivalent MB atoms.

Book Suggested

1. Physical Methods for Chemistry, R.S. Drago, Saunders Compnay.

2. Structural Methods in Inorganic Chemistry, E.A.V. Ebsworth, D.W.H. Rankin and S.

Cradock, ELBS.

3. Infrared and Raman Spectral : Inorganic and Coordination Compounds K. Nakamoto, Wiley.

4. Progress in Inorganic Chemistry vol., 8, ed., F.A. Cotton, vol., 15 ed. S.J. Lippard, Wiley.

5. Transition Metal Chemistry ed. R.L. Carlin vol. 3 dekker.

6. Inorganic Electronic Spectroscopy, A.P.B. Lever, Elsevier.

7. NMR, NQR, EPR and Mossbauer Spectroscopy in Inorganic Chemistry, .V. Parish, Ellis Haywood.

8. Practical NMR Spectroscopy, M.L. Martin. J.J. Deepish and G.J. Martin, Heyden.

9. Spectrometric Identification of Organic Compounds, R.M. Silverstein, G.C. Bassler adn T.C. Morrill, John Wiley.

10. Introduction to NMR spectroscopy, R.J. Abraham, J. Fisher and P. Loftus, Wiley.

11. Application of Spectroscopy of Organic Compounds, J.R. Dyer Prentice Hall.

12. Spectroscopic Methods in Organic Chemistry D.H. Williams, I. Fleming, Tata McGrawHill.

MCH-203: PHYSICAL CHEMISTRY Syllabus MSc CHEMISTRY 2nd- II SemesterSyllabus for DAVV Indore Affiliated Institutions

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (CHEMISTRY) Second-2nd- II Semester Curriculum/ Syllabus

MCH-203: PHYSICAL CHEMISTRY-II Syllabus

Unit-I : Chemical Dynamics

Chemical kinetics: Empirical rate laws, Arrhenius equation, theories of reaction rates, determination of reaction mechanisms.

Kinetics of inorganic mechanisms : Hydrogen- Bromine reaction, Hydrogen- Chlorine Reaction. Decomposition of nitrogen pentaoxide, Decomposition of Ozone.

Kinetics of organic Decompositions : Pyrolysis of acetaldehyde, decomposition of ethane.

Unit-II : Surface Chemistry and Catalysis

Adsorption :Gibbs adsorption isotherm, BET equation and estimation of surface area .

Micelles:Surface active agents, classification of surface active agents, micellization, critical micellar concentration (CMC), factors affecting the CMC of surfactants, thermodynamics of micellization

Concepts of catalysis: Homogenous catalysis, kinetics of enzyme reactions,

Unit –III : Complex and Fast Reaction

Complex Reactions: Opposing reactions, Complex reactions, Parallel reactions , kinetics of free radical polymerization

Fast reactions: Experimental techniques for fast reactions viz., flow method, relaxation method, flash photolysis

Unit-IV: Applied Electrochemistry

Electrochemistry: Nernst equation, electrode kinetics, electrical double layer, Debye-Hückel theory. Voltammetry, Current voltage relationship, characteristics of DME, half-wave potential. Amperometric titrations.

Corrosion: Introduction to corrosion, forms of corrosion, Corrosion monitoring and prevention methods

Books Suggested

1. P.W. Atkins , Physical Chemistry, ELBS.

2. A.K. Chandra, Introduction to Quantum Chemistyry, Tata Mc Graw Hill.

3. Ira N. Levine, Quantum Chemistry, Prentice Hall.

4. K.J. Laidler, Chemical Kinetics. McGraw-Hill.

5. V. Moraoi, Micelles, Theoretical and Applied Aspects, Plenum.

6. A. J. Bard and L. R. Faulkner, Electrochemical Methods: Fundamentals and Applications, John Wiley & Sons: New York.

MCH-202: ORGANIC CHEMISTRY-II Syllabus M.Sc.(CHEMISTRY) 2nd-II Sem Syllabus for DAVV Indore Affiliated Institutions

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (CHEMISTRY) Second-2nd- II Semester Curriculum/ Syllabus

MCH-202: ORGANIC CHEMISTRY-II Syllabus

Unit-I

Common organic reactions and their mechanisms, base catalysed reactions, Stork Enamine  reaction, acid catalysed reactions, reactions of carboxylic acids and their derivatives Reagents in organic synthesis and relevant name reactions, organotransition metal reagents, some transition metal organometallic reactions, phosphorus containing reagents, organosulphur compounds, silicon reagents, boron containing reagents

Unit-II

Eletrophilic aromatic substitution- the arenium ion mechanism, orientation and reactivity, Ipso substitution, aromatic rearrangements Aromatic nucleophilic substitution-SNAr mechanism, SN1 mechanism, benzyne mechanism

Unit-III

Stereochemistry and mechanism of addition to carbon-carbon multiple bonds, addition reactions of alkenes and alkynes involving electrophiles, Birch reduction, epoxidation of alkenes Addition to carbon-hetero multiple bonds, addition to carbonyl compounds, metal hydride reduction, Meerwein-Ponndorf-Verley reduction, Wittig reaction

Unit-IV

Pericyclic reactions, conservation of molecular orbital symmetry, electrocyclic reactions, cycloaddition, sigmatropic rearrangements, the ene reaction, Mobius – Huckel analysis (PMO approach), correlation diagram method

Books Suggested

1. J. March., Advanced Organic Chemistry: Reactions, Mechanisms and Structure, John Wiley

2. P. S. Kalsi. Stereochemistry, Conformation and Mechanism, New Age International

3. Peter Sykes, A guide book to mechanism in Organic chemistry, Orient-Longmans

4. S. M. Mukherji and S. P. Singh, Reaction Mechanism in Organic Chemistry, Macmillan

5. F. A. Carey and R. J Sundberg, Advanced Organic Chemistry, Part A and B, Plenum

6. P. S. Kalsi., Organic Reactions and their Mechanisms, New Age International

MCH-201: INORGANIC CHEMISTRY- II Syllabus M.Sc.(CHEMISTRY) 2nd-II Sem Syllabus for DAVV Indore Affiliated Institutions

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (CHEMISTRY) Second-2nd- II Semester Curriculum/ Syllabus

MCH-201: INORGANIC CHEMISTRY- II Syllabus

Unit-I :Electronic Spectra and Magnetic Properties of Transition Metal Complexes :

Spectroscopic ground states, correlation. Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1-d9 states), calculations of 10Dq, B and β parameters, charge transfer spectra, anomalous magnetic moments, Orbital contribution to magnetic moment, magnetic exchange coupling and spin crossover.

Unit-II : Metal π-Complexes

Metal carbonyl, structure and bonding, vibrational spectra of metal carbonyls for bonding and structural elucidation, important reactions of metal carbonyls; preparation, bonding structure and important reaction of transition metal nitrosyl, dinitrogen and dioxgen complexes; tertiary phosphine as ligand.

Unit-III : Boranes

Classification, preparation, reactivity, bonding and topology of Boranes, carboranes metalloboranes and metallocarbonaes.

Unit-IV : 

Metal Clusters, Chains and Fullerenes Compounds with metal-metal multiple bonds. Isopoly and heteropoly acids and their salts. Fullerenes

Books Suggested :

1. Advanced Inorganic Chemistry, F.A. Cotton and Wilkinson, John Wiley.

2. Inorganic Chemistry, J.E. Huhey, Harpes & Row.

3. Chemistry of the Elements. N.N. Greenwood and A. Earnshow, Pergamon.

4. Inorganic Electronic Spectroscopy, A.B.P. Lever, Elsevier.

5. Magnetiochemistry, R.1. Carlin, Springer Verlag.

6. Comprehensive Coordiantion Chemistry eds., G. Wilkinson, R.D. Gillars and J.A. Mc Cleverty,Pergamon.

Internet Practicals [BCA -208] Syllabus BCA 2nd-II Sem Syllabus for DAVV Indore Affiliated Institutions

 DEVI AHILYA VISHWAVIDYALAYA (DAVV), INDORE

Bachelor Of Computer Applications (BCA) (Full-Time) 
Second-2nd-II Semester Curriculum/ Syllabus 2011-12 Academic Year Onwards

Mathematics – Syllabus 

Internet Practicals [BCA-208] Syllabus /Course contents

MAX.MARKS:25MIN. MARKS: 09

List of suggested Practical work

1. Understanding of a dial up connection through modem.
2. Configuring a computer for e-mail and using outlook express or Netscape messenger.
3. Registering an e-mail address.
4. Understanding of address book maintenance for e-mail.
5. Understanding e-mail drafting.
6. Understanding of different mail program tools.
7. Send and receive function of e-mail.
8. Using the internet for search using search engines.
9. Understanding of sites like BSNL, Rediff, Indianinfoline, Zeenext, AOL, Yahoo, Hotmail,mail city.
10. News services on Internet.
11. Downloading of tutorial from the internet from education sites.
12. Using Internet explorer.
13. Using Netscape navigator.
14. Using Netscape Communication suite.
15. Using front page or notepad etc for web design.

NOTE:

1. Every student will be given 6 periods/week laboratory (1 period = 45 minutes)
2. Every student will work on independent computer (Student: Computer=1:1)

Reference Books:

1. Internet Complete Reference by Sybex Pub.

List of Practicals PROGRAMMING & PROBLEM SOLVING THROUGH C –II [BCA -207] Syllabus BCA 2nd-II Sem Syllabus for DAVV Indore Affiliated Institutions

 DEVI AHILYA VISHWAVIDYALAYA (DAVV), INDORE

Bachelor Of Computer Applications (BCA) (Full-Time) 
Second-2nd-II Semester Curriculum/ Syllabus 2011-12 Academic Year Onwards

 List of Practicals PROGRAMMING & PROBLEM SOLVING THROUGH C –II Syllabus 

PRACTICAL [BCA -207] PROGRAMMING & PROBLEM SOLVING THROUGH C –II Syllabus /Course contents

MAX.MARKS:25    MIN. MARKS: 09

 List of Practicals:

1. To find square root of nos. without using built in function
2. To find factorial of a no. using recursion
3. To reverse digit of number
4. To reverse the given string
5. To search a name in a record of student
6. To create a record having five fields
7. To exchange the value of two variable using function
8. To add two number using pointer
9. To create a file character
10. To read a file
11. To create a file of integer
12. To create file of a record
13. To copy a file
14. To merge two file
15. To find transpose of matrix
16. To find inverse of matrix
17. To convert lower case string into upper case
18. To read character from one text file convert into upper case and length into other file
19. Write a program which ask date of birth in dd/mm/yy format and spell it in word
20. To find out twins prime number
21. To enter a four digit number and print it in all combination
22. Write a mark sheet program using file
23. Write a payroll program using file
24. Partitioning of an array
25. Removal of duplicity in an array
26. Write the following recursive C Function

• ¾    Factorial of a given number
• ¾    Nth Fibonacci number
• ¾    Reverse of a given String
• ¾    Reverse of a give Number
• ¾    Sin(x)

27. Write a c program to create a new data type Date with the help of structure and   typedef. Also write following user defined function for date manipulation.

• ¾    To return next Date,
• ¾    To return next Month,
• ¾    To return next Year,
• ¾    To add few Days in a date
• ¾    To add few Months in a date
• ¾    To add few Years in a date
• ¾    To return the date of the week of a given date.
• ¾    To return Month name from the date.
• ¾    To Display the Date in various format as: Date Display(Date d1, char  *format)  Here Date is the newly created data type. The format string can hold the following values:“DDMMYYYY”, “MMDDYY”, “MON, DD, YYYY”

28. Write a C program to implement myprintf and myscanf functions using Concept of variable number of arguments. (using getch, putch, gets and puts function)
29. Write a C program that creates an Employee text file? Records Are empid, empname, designation, qualification, salary, experience, Research work, address, city phone?
30. Write a C program that manipulates the above text file. The program must implements the operation to modify a record, delete a record and append new records.
31. Write C programs for the following operation to work like DOS Commands:

• ¾    type abc.txt
• ¾    copy source1.txt source2.txt
• ¾    copy source1.txt source2.txt source3.txt source4.txt
• ¾    compare source1.txt source2.txt
• ¾    concat source1.txt source2.txt

32. Write a C program to open two files containing integers (in sorted order) and merge their contents.
33. Write a C program to count the number of vowels, consonants, digits, spaces, other symbols, words and lines in a given text file.
34. Write C code to check if an integer is a power of 2 or not
35. Write a C program to count bits set in an integer.
36. Write a C program to set a particular bit in a given number.
37. Write a C program to reset a particular bit in a given number.
38. IF 5+3+2 = 151022 , 9+2+4 = 183652 , 8+6+3 = 482466 , 5+4+5 = 202541 THEN; 7+2+5 = ? Develop a C program to solve this problem.

NOTE:

1. Every student will be given 6 period /week laboratory(1 period 45 minutes)
2. Every student will be work on independent computer(student: computer =1:1)