MCH-201: INORGANIC CHEMISTRY- II Syllabus M.Sc.(CHEMISTRY) 2nd-II Sem Syllabus for DAVV Indore Affiliated Institutions

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (CHEMISTRY) Second-2nd- II Semester Curriculum/ Syllabus

MCH-201: INORGANIC CHEMISTRY- II Syllabus

Unit-I :Electronic Spectra and Magnetic Properties of Transition Metal Complexes :

Spectroscopic ground states, correlation. Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1-d9 states), calculations of 10Dq, B and β parameters, charge transfer spectra, anomalous magnetic moments, Orbital contribution to magnetic moment, magnetic exchange coupling and spin crossover.

Unit-II : Metal π-Complexes

Metal carbonyl, structure and bonding, vibrational spectra of metal carbonyls for bonding and structural elucidation, important reactions of metal carbonyls; preparation, bonding structure and important reaction of transition metal nitrosyl, dinitrogen and dioxgen complexes; tertiary phosphine as ligand.

Unit-III : Boranes

Classification, preparation, reactivity, bonding and topology of Boranes, carboranes metalloboranes and metallocarbonaes.

Unit-IV : 

Metal Clusters, Chains and Fullerenes Compounds with metal-metal multiple bonds. Isopoly and heteropoly acids and their salts. Fullerenes

Books Suggested :

1. Advanced Inorganic Chemistry, F.A. Cotton and Wilkinson, John Wiley.

2. Inorganic Chemistry, J.E. Huhey, Harpes & Row.

3. Chemistry of the Elements. N.N. Greenwood and A. Earnshow, Pergamon.

4. Inorganic Electronic Spectroscopy, A.B.P. Lever, Elsevier.

5. Magnetiochemistry, R.1. Carlin, Springer Verlag.

6. Comprehensive Coordiantion Chemistry eds., G. Wilkinson, R.D. Gillars and J.A. Mc Cleverty,Pergamon.