MCH-202: ORGANIC CHEMISTRY-II Syllabus M.Sc.(CHEMISTRY) 2nd-II Sem Syllabus for DAVV Indore Affiliated Institutions

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (CHEMISTRY) Second-2nd- II Semester Curriculum/ Syllabus

MCH-202: ORGANIC CHEMISTRY-II Syllabus

Unit-I

Common organic reactions and their mechanisms, base catalysed reactions, Stork Enamine  reaction, acid catalysed reactions, reactions of carboxylic acids and their derivatives Reagents in organic synthesis and relevant name reactions, organotransition metal reagents, some transition metal organometallic reactions, phosphorus containing reagents, organosulphur compounds, silicon reagents, boron containing reagents

Unit-II

Eletrophilic aromatic substitution- the arenium ion mechanism, orientation and reactivity, Ipso substitution, aromatic rearrangements Aromatic nucleophilic substitution-SNAr mechanism, SN1 mechanism, benzyne mechanism

Unit-III

Stereochemistry and mechanism of addition to carbon-carbon multiple bonds, addition reactions of alkenes and alkynes involving electrophiles, Birch reduction, epoxidation of alkenes Addition to carbon-hetero multiple bonds, addition to carbonyl compounds, metal hydride reduction, Meerwein-Ponndorf-Verley reduction, Wittig reaction

Unit-IV

Pericyclic reactions, conservation of molecular orbital symmetry, electrocyclic reactions, cycloaddition, sigmatropic rearrangements, the ene reaction, Mobius – Huckel analysis (PMO approach), correlation diagram method

Books Suggested

1. J. March., Advanced Organic Chemistry: Reactions, Mechanisms and Structure, John Wiley

2. P. S. Kalsi. Stereochemistry, Conformation and Mechanism, New Age International

3. Peter Sykes, A guide book to mechanism in Organic chemistry, Orient-Longmans

4. S. M. Mukherji and S. P. Singh, Reaction Mechanism in Organic Chemistry, Macmillan

5. F. A. Carey and R. J Sundberg, Advanced Organic Chemistry, Part A and B, Plenum

6. P. S. Kalsi., Organic Reactions and their Mechanisms, New Age International