MCH-204: Magnetic Resonance and Mössbauer Spectroscopy Syllabus M.Sc.(CHEMISTRY) 2nd-II Sem Syllabus for DAVV Indore Affiliated Institutions

DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus

M.Sc. (CHEMISTRY) Second-2nd- II Semester Curriculum/ Syllabus

MCH-204: Magnetic Resonance and Mössbauer Spectroscopy Syllabus

Unit-I: Nuclear Magnetic Resonance Spectroscopy

Nuclear spin, nuclear resonance, saturation, shielding of magnetic nuclei, chemical shift and its measurements, factors, influencing chemical shift, deshielding, spin-spin interactions, factors influencing coupling constant "j" Classification (AXB, AMX, ABC, A2B2 etc.). spin decoupling; basic ideas about instrument, NMR studies of nuclei other than protin-13C, 19F and 31P. FT  MR.

Unit-II : Nuclear Quadrupole Resonance Spectroscopy

Quadrupole nuclei, quadrupole moments, electric field gradient, coupling constant, splitting. Applications.

Unit-III : Electron Spin Resonance Spectroscopy

Basic principles, Hyperfine coupling, Isotropic and anisotropic hyperfine coupling contstnats, spin polarization for atoms and transition metal ions, spin-orbit coupling and significance of gtensors, factors affecting the 'g' value. Zero field splitting and Kramer's degeneracy.. spin Hamiltonian, spin densities and Mc Connell relationship. Applications.

Unit IV : Mössbauer Spectroscopy

Basic principles, spectral parameters and spectrum display. Application of the techniqueto the studies of (1) bonding and structures of Fe+2 and Fe+3 compounds including those of intermediate spin, (2) Sn+2 and Sn+4 compounds nature of M-L bond, coordination number, structure and (3) detection of oxidation state and inequivalent MB atoms.

Book Suggested

1. Physical Methods for Chemistry, R.S. Drago, Saunders Compnay.

2. Structural Methods in Inorganic Chemistry, E.A.V. Ebsworth, D.W.H. Rankin and S.

Cradock, ELBS.

3. Infrared and Raman Spectral : Inorganic and Coordination Compounds K. Nakamoto, Wiley.

4. Progress in Inorganic Chemistry vol., 8, ed., F.A. Cotton, vol., 15 ed. S.J. Lippard, Wiley.

5. Transition Metal Chemistry ed. R.L. Carlin vol. 3 dekker.

6. Inorganic Electronic Spectroscopy, A.P.B. Lever, Elsevier.

7. NMR, NQR, EPR and Mossbauer Spectroscopy in Inorganic Chemistry, .V. Parish, Ellis Haywood.

8. Practical NMR Spectroscopy, M.L. Martin. J.J. Deepish and G.J. Martin, Heyden.

9. Spectrometric Identification of Organic Compounds, R.M. Silverstein, G.C. Bassler adn T.C. Morrill, John Wiley.

10. Introduction to NMR spectroscopy, R.J. Abraham, J. Fisher and P. Loftus, Wiley.

11. Application of Spectroscopy of Organic Compounds, J.R. Dyer Prentice Hall.

12. Spectroscopic Methods in Organic Chemistry D.H. Williams, I. Fleming, Tata McGrawHill.