DEVI AHILYA VISHWAVIDYALAYA, DAVV INDORE Syllabus
M.Sc. (CHEMISTRY)Third-3rd-III Semester Curriculum/ Syllabus
MCH-302: Photochemistry Syllabus
UNIT-I : Photochemical Reactions
Interaction of electromagnetic radiation with matter, types of excitations, fate of excited molecule, quantum yield, transfer of excitation energy, actinometry.
UNIT-II : Determination of Reaction Mechanism
Classification, rate constants and life times of reactive energy state determination of rate constants of reactions. Effect of light intensity on the rate of photochemical reactions, Types of
photochemical reactions-photo dissociation, gas-phase photolysis.
UNIT-III : Photochemistry of Alkene
Intramolecular reactions of the olefinic bond-geometrical isomerism, cyclisation reactions, rearrangement of 1,4- and 1,5-dienes.
Photochemistry of Aromatic Compounds
Isomerisations, Additions and Substitutions.
UNIT-IV : Photochemistry of Carbonyl Compounds
Intramolecular reactions of carbonyl compounds-saturated, cyclic and acyclic,,γ- unsaturated and α,- unsaturated compounds, cyclohexadienones. Intermolecular cycloaddition reactionsdimerisations and oxetane formation.
Miscellaneous Photochemical Reactions
Photo-Fries reactions of anilides, Photo-Fries rearrangement. Barton reaction. Singlet molecular oxygen reaction. Photochemical formation of smog. Photodegration of polymers. Photochemistry of vision
Books Suggested
1. K.K. Rothagi-Mukheriji, Fundamentals of photochemistry, Wiley-Eastern.
2. A Gilbert and J. Baggott, Essentials of Molecular Photochemistry, Blackwell Scientific Publication.
3. N.J. Turro, Molecular Photochemistry, Benjamin.
4. A. Cox and T. Camp, Introductory Photochemistry, McGraw Hill.
5. R.P. Kundall and A. Gilbert, Photochemistry, Thomson Nelson.
6. J. Coxon and B.Holtom, Organic Photochemistry, Cambridge University Press.
7. C H Dupuoy and O L Chapman Molecular Reactions and Photochemistry, Prentice Hall
8. J Kagan, Organic Photochemistry, Academic Press
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